Pyrrole derivatives are widely recognized for their presence in biologically active natural products, pharmaceuticals, and advanced functional materials. Given their significant role in systems such as heme, chlorophyll, and vitamin B₁₂, the development of efficient synthetic approaches to functionalized pyrroles remains a crucial objective in organic chemistry. In this study, we investigated a three-step synthesis of β-substituted pyrrole derivatives based on aromatic-substituted 1,3-dicarbonyl compounds and 2,3-dibromoprop-1-ene. New 2-phenyl tetra substituted pyrroles were synthesized in a superbasic medium comprising t-BuOK/DMSO in t-BuOH. The structure of new synthesized compounds were confirmed by 1H and 13C NMR spectroscopy.