CHEMISTRY & MATERIALS SCIENCE
BAKU STATE UNIVERSITY JOURNAL of
CHEMISTRY & MATERIALS SCIENCE
ISSN: 3006-7073 (ONLINE);     
PHASE RELATIONS IN THE AGI-AG7GESE5I-GESE2 SYSTEM
Received: 03-Sep-2025 Accepted: 30-Oct-2025 Published: 31-Oct-2025 Read PDF Download PDF
Nurten Bayramova; Ilaha Huseynova; Elvira Melikova; Samira Imamaliyeva
DOI:
Abstract
Phase equilibria in the AgI-Ag7GeSe5I-GeSe2 system were studied by differential thermal and X-ray diffraction analysis. T-x phase diagrams of boundary systems, liquidus surface projection and a number of internal vertical sections of the T-x-y diagram were constructed. It was found that all three boundary systems are quasi-binary and form eutectic phase diagrams. The AgI-Ag7GeSe5I-GeSe2 system is a quasi-ternary plane of the corresponding quaternary system and belongs to the type with invariant eutectic crystallizing at 525 0C. The liquidus surface projection consists of 3 regions corresponding to the primary crystallization of the α-phase based on Ag7GeSe5I, as well as high-temperature modifications of the AgI and GeSe2 compounds. The liquidus surfaces of HT-GeSe2 and the α-phase, which have a higher melting point, occupy very large areas, while the liquidus surface of the HT-AgI phase is located in a small region near the corresponding vertex of the concentration triangle.

Digər məqalələr

SUBMIT MANUSCRIPT
Submit your manuscript and publish it with Baku State University Journals.
Submit >>
Jurnal seçimi
SIGN UP FOR EMAIL ALERTS
An email notification is an email sent to inform you about updates Baku State University Journals, like new issues, news, or scheduled events, etc.
Sign Up >>